地震地质 ›› 2020, Vol. 42 ›› Issue (5): 1229-1239.DOI: 10.3969/j.issn.0253-4967.2020.05.013

• 研究论文 • 上一篇    下一篇

蒙脱石的弹性性质实验

张明洋, 杨晓松*   

  1. 中国地震局地质研究所, 地震动力学国家重点实验室, 北京 100029
  • 收稿日期:2020-01-13 修回日期:2020-08-25 出版日期:2020-10-20 发布日期:2021-01-06
  • 通讯作者: *杨晓松, 男, 1959年生, 研究员, 主要研究方向构造地质学及岩石物理学, E-mail: xsyang@ies.ac.cn。
  • 作者简介:张明洋, 男, 1990年生, 2015年于中国地质大学(北京)获地球物理学专业学士学位, 现为中国地震局地质研究所构造地质学专业在读硕士研究生, 主要研究方向为高温高压岩石物理, 电话: 18810553074, E-mail: 837306074@qq.com。
  • 基金资助:
    国家自然科学基金(41672197,41972209)和中国地震局地震行业科研专项(201508018)共同资助

EXPERIMENTAL STUDIES ON ELASTIC PROPERTIES OF MONTMORILLONITE

ZHANG Ming-yang, YANG Xiao-song   

  1. State Key Laboratory of Earthquake Dynamics, Institute of Geology,China Earthquake Administration, Beijing 100029, China
  • Received:2020-01-13 Revised:2020-08-25 Online:2020-10-20 Published:2021-01-06

摘要: 蒙脱石通常在断层岩、 泥岩、 碎屑岩的储集层中富集, 其弹性性质对地震测深及声波测井的解译具有重要参考价值。 然而, 不同学者获得的蒙脱石体积模量的差异非常大, 变化范围为6~63GPa。 因此, 开展精细的实验研究以确定蒙脱石的弹性性质尤为重要。 文中利用LR-White胶(简称LRWG)为介质, 制备出纯LRWG单相体、 蒙脱石-LRWG二相体和石英-LRWG二相体实验样品。 通过单轴冷压的实验方式, 在0~600MPa的压强范围内测量了样品密度、 长度随压强的变化, 并分别计算了LRWG、 蒙脱石和石英的单轴压缩系数。 实验获得石英的体积模量为37.49GPa, 与前人的实验结果37GPa一致, 显示了所采用的实验方式和数据处理方法的可靠性和有效性。 4组实验得到的蒙脱石体积模量分别为10.44GPa、 6.36GPa、 8.34GPa和7.86GPa, 其平均体积模量为8.25GPa, 实验结果为蒙脱石弹性性质的研究提供了新的数据。 此外, 本实验方法对于研究黏土矿物及断层岩压缩系数也具有重要的启示作用。

关键词: 压缩系数, 体积模量, 单轴冷压, 蒙脱石, 石英

Abstract: As clay minerals, montmorillonite is usually enriched in fault rocks, mudstones and clastic rocks. It is important to measure its elastic properties accurately for seismic sounding and interpretation of sonic logging. Many researches on the elastic properties of clay minerals have been carried out by predecessors, including the theoretical modelling of the elastic modulus of clay, the experimental determination of the elastic modulus of aggregates of clay minerals by cold pressing and the calculation of clay elastic modulus based on the corresponding elastic modulus of shale and two-phase bodies composed of mixture of clay-epoxy, and so forth. The comparison results of these modulus obtained by different methods show a huge difference. Previous investigations display a massive gap on the bulk modulus of montmorillonite ranging from 6GPa to 63GPa. Here, we present the new results of bulk modulus of montmorillonite based on uniaxial compression experiments on the two-phase bodies composed of mixture of montmorillonite and LR-White glue(hereinafter referred to as LRWG)and of quartz-LRWG performed at the pressure of 0.1~600MPa and at room temperature. On the base of the changes of sample length and density with pressure, the uniaxial compressibility of LRWG, quartz and montmorillonite are obtained. The internal porosity in these starting materials(two-phase bodies)were checked by scanning electron microscope to ensure the porosity within the range of allowable error. Observations show that the porosity in the starting materials is extremely low. Although very small amount of cracks inevitably exist at the boundaries between the montmorillonite aggregate and LRWG, attributed to drying shrinkage during sample preparation(heating and solidification), the pores disappear at the pressure increasing to 200MPa approximately. Hence, the samples could be regarded as pure two-phase bodies when the pressure is higher than 200MPa. After the uniaxial compression, the mineral particles in the specimen exhibit uniform distribution and no anisotropies are observed. In the initial stage of pressurization, the non-linear shortening of the montmorillonite-LRWG sample is explained to rapid reduction of the pores which is expected to be between the starting materials and sample chamber and between montmorillonite aggregate and LRWG. During the pressure range from 250MPa to 600MPa, the length of specimen linearly decreases with increasing pressure. The calculated bulk modulus of quartz is 37.49GPa which is consistent with previous report of 37GPa. The bulk modulus of montmorillonite of 10.44GPa, 6.36GPa, 8.34GPa and 7.86GPa with the average of 8.25GPa are obtained. The variation range of the bulk modulus of montmorillonite is about ±2GPa, which is significantly better than the previous experimental results. The experiments provide both reliable data and an effective technique for investigating the elastic properties of clay reservoir.

Key words: quartz, montmorillonite, compressibility, bulk modulus, uniaxial compression experiment

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