Terrestrial in-situ cosmogenic nuclide dating(TCND)is one of the most important geochronological techniques for the paleoseismic study of bedrock fault scarps, landslides, and rock avalanches. With many target minerals, due to its uncomplicated composition, widespread occurrence, and simple chemical treatment, Quartz has emerged as an ideal dating material for terrestrial in-situ cosmogenic nuclides dating methods, such as 14C, 10Be, 21Ne, and 26A1. Prior to accelerator mass spectrometry measurement, the separation of pure quartz from field-collected rock samples was a pivotal step in TCND. However, the elevated aluminum content in quartz samples undermines the reliability of TCND results. Generally, most of the aluminum content in samples originates from impurities like feldspar. To ensure accurate dating outcomes, the content of Al in samples should be reduced to less than 200 ppm. Therefore, effective separation of feldspar and quartz in samples and obtaining pure quartz is the first step in TCN dating. The conventional HF/HNO3 etching method to separate and purify quartz is widely utilized, but it is time-consuming and low-efficiency. Particularly during the HF/HNO3 etching stage when dealing with granitic samples containing abundant feldspars and mica impurity minerals necessitates repeated treatments to eliminate feldspars completely; this not only increases etching cycles but also leads to sample loss significantly. It has a great impact on the application of in-situ cosmogenic nuclide dating in active tectonics. Consequently, physically separating quartz from samples before chemical purification can effectively shorten the chemical etching duration while the flotation separation method can effectively remove most gangue minerals in quartz and achieve preliminary purification of quartz.
This article presents a laboratory-integrated flotation purification device and proposes enhancements to the conventional quartz etching process in order to improve its purification efficiency. The purification device uses dodecylamine as the collector, hydrofluoric acid as the feldspar activator, nitric acid as the regulator, and eucalyptus oleanol as the foaming agent. The bubbling component within the device provides sufficient carbon dioxide bubbles to float out feldspar and other minerals in the sample reversely. To evaluate its efficacy in flotation separation, enrichment, and purification, this study conducted tests on two commonly encountered bedrock samples of granitic gneiss and quartzite.
Observation results under a stereomicroscope show that the quartz content in the quartz component after floating is more than 90%. The etching results of the whole rock and the floated quartz components show that after etching 2-3 times with HF/HNO3, the Al concentration can be reduced to less than 200ppm, which fully meets the requirement of cosmogenic nuclide dating. The quartz separated by flotation from cryptocrystalline quartzite samples can also reach the dating requirements after etching 7-8 times.
Compared to direct etching following bulk-rock sample crushing, this approach reduces etching time by over a half, significantly minimizing reagent consumption for HF/HNO3 etching and thereby enhancing TCND efficiency. The bubbling power section of our flotation device directly introduces carbon dioxide gas into the flotation liquid to increase the bubble content in the slurry. Consequently, there is improved collision and contact between quartz and feldspar particles with bubbles, resulting in enhanced flotation effectiveness. This system can be effectively employed for separating feldspar from other impurity minerals present in gneiss samples. The proposed flotation process in this study is straightforward and user-friendly while allowing flexibility in adjusting sample quantities ranging from tens to hundreds of grams as required. Furthermore, this high-efficiency flotation separation system may offer insights into processing zircon, apatite, and other dating samples.
Using the Monte Carlo random sampling method, a set of probabilistic seismic hazard analysis calculation programs that integrates our country’s traditional planar potential seismic source zone and three-dimensional fault sources is developed. The program is not only suitable for our country’s traditional regional area sources, but also considers the rupture scale of earthquakes and is compatible with the probabilistic seismic hazard calculation of three-dimensional fault sources. The algorithm developed in this paper efficiently realizes the three-dimensional simulation of the seismic event set of the fault source and introduces the earthquake rupture scale into the probabilistic seismic hazard analysis calculation in China, which significantly improves the rationality of the seismic hazard calculation in the near-fault area. In order to improve the execution efficiency of the program, the algorithm adopts the method of filling grid points in the planar potential seismic source zone in advance and randomly simulating the uniform distribution of seismic events in the planar potential seismic source zone. For the seismic hazard calculation of elliptical attenuation relationship, the algorithm uses pre-constructed three-dimensional matrices of the distance of the ellipse minor axis under different magnitudes, distances, and different angles between sites and the ellipse long axis direction of potential seismic source zone, and directly obtains the corresponding distance of ellipse minor axis through table look-up and interpolation. The algorithm developed in this paper avoids the problem of low computational efficiency in the iterative approximation of the distance of the ellipse minor axis. The mathematical expression of the three-dimensional fault source is based on the Frankel fault plane form of the 2002 edition of the National Seismic Hazard Map of the United States. The surface track and average dip Angle of the fault are used to create the rectangular fault plane, in which the dip direction of each rectangle is always perpendicular to the strike of its local fault segment. To maintain the coordination between the rupture area and the magnitude, the rupture of the earthquake occurring on the fault plane should not exceed the fault plane or the combination of fault planes. If the boundary of the rupture plane is outside the fault boundary, the entire rupture plane will move so that the boundary of the entire rupture plane matches the boundary of the fault plane. Using the probabilistic seismic hazard program of the Seismic ground motion parameters zonation map of China(2015)and the algorithm developed in this paper, the regional seismic hazard of the study area including Changsha-Zhuzhou-Xiangtan of the urban agglomeration in Hunan Province with moderate to strong seismic activity are calculated. Seismic hazard at different probability levels(return periods of 50.8, 475 and 2 475 years, respectively)for the Changde near-fault sources and Zhuzhou sites are also computed. The comparative study shows that the procedure of the Seismic ground motion parameters zonation map of China(2015)underestimates the seismic hazard near the three-dimensional fault source, and the degree of underestimation becomes more significant as the probability level decreases. Considering the influence of the earthquake rupture scale at the low exceedance probability level, the decomposition results of the seismic hazard for sites near fault show that the contribution of the seismic hazard is different from that of the traditional method of the Seismic ground motion parameters zonation map of China(2015), which mainly focuses on the earthquake of high magnitude. However, earthquakes of all magnitudes on the fault source can contribute to the seismic hazard, but the proportion of high magnitudes is the largest. Finally, an example verifying the probabilistic seismic hazard program(data set 1 case 10)from the Pacific Earthquake Engineering Research Center(PEER)is used to verify the reliability of the algorithm developed in this paper.
It is difficult to use traditional trenching and field geological investigation to yield the age of paleoseismic events along active fault in western mountainous areas of China where the geomorphic trace mark and sediments are often eroded or altered by human activities. The recurrence interval of paleoearthquake possesses greater uncertainty. It is necessary to yield ages of paleoearthquake event from different ways and examine the reliability of paleoearthquake results. In these regions, an earthquake with magnitude greater than 7 can produce rock avalanches around 200~400km away from the epicenter, such as the Wenchuan earthquake in 2008, due to their structure setting of strong neotectonic activity and the higher topographic relief. Therefore, the seismic bedrock landslide and rock avalanche can record the occurrence time, intensity and damage of strong earthquake in the mountainous area. This provides a new way to assess the frequency and intensity of paleoearthquake occurring in the intraplate continental areas(such as the north-south seismic zone)where strong earthquakes recurred for hundreds to thousands of years based on the seismic landslide records. Identifying ancient earthquake bedrock collapse relics in Quaternary deposits and accurately determining their ages will not only help broaden the study on the recurrence history of active fault, but also assess the earthquake risk in mountainous area.As shown by previous studies, the Schmidt-hammer exposure-age dating(SHD)method is a relatively simple, rapid, cheap and non-destructive in-situ exposure age dating method. In this study, ancient earthquake bedrock landslides and rock avalanches with known historical records distributed on the Qinling northern piedmont fault and the Huashan piedmont fault are used to preliminarily establish the rock weathering factor with age calibration curve. The rebound values of rock surface at dozens of sampling sites of each rock avalanche and landslide are measured by Schmidt hammer and analyzed statistically. The weathering factor of the exposed rock of each rock avalanche and landslide is calculated and the solution of SHD method is discussed. The reliability of SHD is evaluated according to the measured data and the records of historical age. The main conclusions are as follows:(1)The Schmidt hammer rebound value of rock surface at three ancient earthquake bedrock landslides and rock avalanches is negatively correlated with their historical ages. The older the historical record age, the lower the average rebound value of the rock, and vice versa. Based on the statistical analysis of weathering factors of rocks of bedrock landslides and rock avalanches, a preliminary age calibration curve is obtained as T=(19 723±888)×fw-(2 145±166). This curve can be used to infer the bedrock landslides and rock avalanches of more than 5×102 a BP, and it provides a new relative dating method for the ancient bedrock landslide and rock avalanches within the age of 3 000a BP in the northern margin of the Qinling Mountains.(2)Under the climatic and lithological conditions of the northern margin of the Qinling Mountains, the relative ages of bedrock landslide and rock avalanches can discriminate the interval of millennium scale according to the rock rebound value measured by Schmidt hammer. However, it cannot distinguish the difference in weathering degree of the bedrock landslide and rock avalanches with the interval of less than 500 years.(3)The Schmidt hammer rebound value measured repeatedly on fresh rocks shows that the fluctuation range of the rebound values is small, within the value of 0-3, which is helpful to rapidly select qualified sampling sites for terrestrial in-situ cosmogenic nuclide dating(TCND). Thus, the Schmidt hammer value can be used to evaluate whether the rock samples have the problem of nuclide inheritance induced by complex exposure history such as post-exposure and secondary transportation. This would introduce greater objectivity to the sample selection and possibly require less samples, thus reducing the costs; meanwhile, it will improve the dating efficiency and ensure the reliability of TCND. Therefore, SHD method is a valuable complementary method to TCND.(4)Under the climatic and lithological conditions in the northern margin of the Qinling Mountains, the rebound value decreases by (25%±1%) for rocks after weathering for 2ka, by (16%±1%) for 1ka, and by (15%±1%) for 0.5ka.
The Karakoram Fault is located in the west of the Qinghai-Tibet Plateau and crosses Kashmir, Xinjiang and Tibet in China. It is a large normal dextral strike-slip fault in the middle of the Asian continent. As a boundary fault dividing the Qinghai-Tibet Plateau and the Pamir Plateau-Karakoram Mountains, the Karakoram Fault plays a role in accommodating the collision deformation between the Indian plate and the Eurasian plate and in the tectonic evolution of the western Qinghai-Tibet Plateau. The fault trace in Ngari area is clear and the faulted landforms are obvious, which show strong activity characteristics in late Quaternary. As a large active fault, only one earthquake of magnitude 7 has been recorded on the Karakoram Fault since the recorded history, namely, the Tashkurgan earthquake of 1895 at its north end. There are no records of strong earthquakes of magnitude≥7 along the rest of the fault, and no paleo-seismic research has been carried out. Ages of recent strong earthquake activity and earthquake recurrence intervals are not clear, which greatly limit the accuracy of seismic risk assessment. In this study, we investigated the fault geometry and faulted landforms in Ngari area, collected OSL samples of the faulted landforms and sag ponds in Zhaxigang, Menshi and Baga towns and preliminarily discussed the ages of recent strong earthquake activity.
Study shows that the fault can be divided into three sections by Zhaxigang town and Suoduo village, and the structure and properties of each section are significantly different. In west Zhaxigang town section, the fault is dominated by dextral strike-slip with certain vertical movement, it is almost straight on the surface, with river terraces, alluvial-proluvial fans and water system faulted ranging from tens to hundreds of meters. In Zhaxigang town to Suoduo village section, the normal faulting is remarkable, the main fault constitutes the boundary fault between Ayilari Mountain and Gar Basin; fault facets and fault scarps are common along the fault line, there are also secondary faults with the same or opposite dip as the main fault developed near the piedmont basin. In east Suoduo village section, the main part of the fault is located at the south foot of Gangdise Mountain, and in addition to the piedmont fault, several approximately parallel faults are also developed on the southern alluvial-proluvial fans and moraine fans which are mainly dextrally faulted with certain vertical component.
According to the analysis of the faulted landforms and dating of the OSL samples collected from the sag ponds and faulted landforms in the west of Zhaxigang town, the east of Menshi town and the east of Baga town, the ages of recent strong earthquake activity on the fault are analyzed as follows. In the west of Zhaxigang town, the age of recent strong earthquake activity of the fault is constrained to be close to 2.34kaBP according to the average OSL dating results of KKF-3 and KKF-4. In the east of Menshi town, the recent earthquake activity age of fault f2 is 4.67~3.01kaBP, but closer to 3.01kaBP according to the OSL dating results of KKF-11 of the youngest faulted geomorphic surface and average OSL dating results of KKF-6 and KKF-13 collected from sag ponds. In the area near Angwang village, Baga town, it is inferred that the recent strong earthquake activity age of the fault is close to 2.54kaBP according to the OSL dating results of KKF-2 collected from sag pond. If the faults of above three places are active at the same time, the age of recent strong earthquake activity of the fault is close to 2.63kaBP. The Karakorum Fault in Ngari area has obvious segment boundaries, and the activity of each segment and in its internal branch faults is most likely to be independent.
The earthquake recurrence interval on the fault is estimated to be 2.8ka according to the slip rate and the amount of displacement. From the above analysis, it can be seen the time since the last strong earthquake activity of Karakorum Fault may have been very close to the interval of earthquake recurrence. If the fault is characterized by a quasi-periodic in-situ recurrence, the energy accumulation in the fault may have reached a very high degree and the risk of recurrence of strong earthquake events of the fault may be very high, so more attention should be paid and more detailed research on the paleo-earthquake events and recurrence intervals should be carried out as quickly as possible.
Based on the 6 campaigns relative gravity observation data of the Xichang gravity survey network from 2012 to 2014, we analyze the gravity change patterns between two adjacent observation campaigns, the dynamic patterns of cumulated gravity change relative to the first campaign and the gravity time-variation at some stations near the epicenter of Ludian earthquake in the study area. We find that there was no obvious cumulative trend anomaly before the Ludian MS6.5 earthquake 2 years ago, and the possible precursor signals are related to the gravity difference changes of the stations located at the two sides of the fault slip surface during the period of 2014-03—2014-06. Using equivalent source model to inverse these gravity anomalies, we deduce the density changes in 10-5g/cm3 orders of magnitude to the depth of epicenter. It is inferred that the change of the mass source in the short time may be related with the filling or migration of pore fluid in the crust medium. Under the equal dynamic condition of short-time tectonic movement, fault slip in the seismogenic zone may be triggered due to fluid migration and filling, thus, resulting in generation of earthquake.
Based on the 1: 50 000 geological mapping of active fault, the paper investigates the stratum, topography and faulted landforms of the northern marginal fault of Emei Platform, and preliminarily divides the northern marginal fault of Emei Platform into three sections by two stepovers near Tanjiazhuang Village and Nanliu Village according to different fault activity of each section. At west of Tanjiazhuang Village is a loess platform, and the high terrain scarp can be seen from the northern margin. The height of scarp decreases progressively and the slope becomes gentle westwards at the place between Nanchi Village and Xikang Village, and to the place near Xiaoliang town, we cannot see obvious terrain scarps. The faulted sections can only be seen in the gullies which cross the terrain scarp at the south of Guozhuang Village and Tanjiazhuang Village. The fault dislocates the Pliocene red clay and the middle Pleistocene Lishi loess and covered by Malan loess; continuous paleosoil can be seen across the terrain scarp in some gullies. These indicate that in this section the fault was active in the early middle Pleistocene and its activity becomes weaker or no longer active after that. The fault in the section between Tanjiazhuang Village and Nanliu Village can be divided into three parts by Shidian Village and Jinming Village, which are named, from west to east in sequence according to each faulted landform, the northern marginal fault of lacustrine terrace, the piedmont fault of Zijin Mountain and the northern marginal fault of loess platform. The fault transition area between each part is continuous and the fault is in linear distribution, so we see the whole fault section as having the same activity. In this section the Holocene diluvial fan is faulted. At least two plaeoearthquake events happened since Holocene, and the latest activity is in (2.00~1.29) ka BP according to Renzhuang trench and Jinsha trench, which can be well compared with former researches. The fault slip rate is over 0.33mm/a in the section south of Maguduo Village and is more than 0.36mm/a according to Renzhuang trench since the later period of the late Pleistocene. In the section between Nanliu Village and Xizhangpo Village, the fault distributes along the frontal edge of the diluvial platform and is covered by thick loess. A 50~200m high linear terrain scarp formed due to the activity of fault can be seen along the frontal edge especially in the part between Xunwang Village and Xulu Village. At north of Wuzhai Village, the height of scarp decreases progressively and to the place near Xizhangpo Village, the terrain scarp cannot be seen clearly. In this section, Malan loess is faulted, which indicates that this fault section has been active since the late Pleistocene, but the evidence of Holocene fault activity has not been obtained yet due to the non-development of Holocene stratum. The fault slip rate is no less than 0.1mm/a since the late Pleistocene according to the faulted section at south of Xunwang Village.
Kouquan Fault is located in the north part of Shanxi graben which controls the west edge of Datong Basin.Two M6 1/2 earthquakes happened in the west side of basin in historical time,and there has been a concern about the future hazard of the fault.However,previous researches on Kouquan Fault were limited only in several points,especially,there was lack of measurements and dating data.Based on the 1 :50000 geological mapping of Kouquan Fault,the paper investigates the late Quaternary faulted landforms of its middle part(the part between Shangshenquan village and Yangjiayao village),combining with remote sensing interpretation of Spot image and field validating of the study area,and finally obtains the late Quaternary dip-slip rates of this fault.Five stratiform landforms can be found from piedmont to riverbed.The topmost part(the fifth geomorphic surface)is piedmont erosion surface which might be the planation surface of Tangxian period; the fourth geomorphic surface,which formed in the end of the middle Pleistocene to the early stage of late Pleistocene,consists of T3 terrace of big rivers and diluvium mesas developed on piedmont; the third and the second geomorphic surface can be found in valleys and are represented as T2 and T1 terrace,respectively.Diluvium mesas of the same period formed in the end of the late Pleistocene and the middle stage of Holocene are distributed in different parts in front of mountains.The first geomorphic surface is flood plain and modern alluvial fans at mountain front.According to OSL dating and radiocarbon dating of different terraces,we obtained the ages below: T3,no less than 70ka; T2,about 33ka; T1,4~8ka.The characteristic of faulted landform of the research area is different due to the fault activity of different parts.In the segment with intense faulting,the fault trace is obvious,and we could see fault scarps and triangular facets in the field,low river terraces such as T1 and T2 had been faulted; In the segments with less activity,the fault trace is unclear,the older fault scarps have gentle slope due to river erosion and reverse slope,and there is no evidence of faulted low terraces.Based on faulted landforms of the different terraces,we divide the middle part of Kouquan Fault into three sections by Baipo village and Chanfang village.At south of Baipo village,the diluvium mesas corresponding to the period of T3 were faulted,but there is no evidence found dislocating the younger geomorphic surface.This indicates that this part has not been active since Holocene; T2 and the older terraces were faulted between Baipo village and Chanfang village; the evidence of offset of T1 terrace could be seen at the north of Chanfang village,especially in the part between Xiaoyukou village and Louzikou village.In the section north of Chanfang village,the fault throw of T1 terrace is 50cm in Dayukou village,over 3m in the part between Xiaoyukou village and Louzikou village,and 25~30cm in the part between Shijing village and Ermaokou village; the fault throw of T2 terrace is 5.7m in the part between Chanfang village and Dayukou village,over 17.5m in the part between Xiaoyukou village and Louzikou village,and 13m in the part between Shijing village and Ermaokou village. We calculated the slip rates combining with the fault throw of T2 terrace at different sites,and the results are as follows: >0.53mm/a between Xiaoyukou village and Louzikou village,0.4mm/a between Shijing village and Emaokou village and 0.17mm/a between Chanfang village and Dayukou village.These maybe indicate that the late Quaternary activity of the fault was centered on the part between Xiaoyukou village and Louzikou village,and became weaker towards both sides.