On July 22, 2013, an MS6.6 earthquake occurred at the junction of Minxian and Zhangxian. After the earthquake, magnetotelluric(MT)measurement was carried out at 45 sites along the NE-oriented profile across the West Qinling orogen(the west segment)and the earthquake area. Remote reference, "robust", and phase tensor decomposition techniques were used to process the MT data, and the NLCG two-dimensional inversion method was adopted to get the deep electrical structures. The deep electrical structure images indicate that there exists an inverted trapezoidal high-resistivity layer in the West Qinling orogenic belt(west segment)at the depth from the surface to about 20km deep, which is shallow in the northeast and southwest and deep in the middle. Under the high-resistivity layer is a low-resistivity layer, and they conjoin each other. There is a low-resistivity layer in the Songpan-Ganzi block(north part)at the southwest side of West Qinling orogenic belt(west segment)under the depth of 20km in the lower crust, which is shallow in the northeast and deep in the southwest, and the Longxi Basin at its northeast has a stable layered structure, suggesting that West Qinling orogenic belt(west segment)is being subject to the northward extrusion of the Songpan-Ganzi block and southward resistance of the Longxi Basin. The East Kunlun Fault(Tazang segment)faulted the low-resistivity layer in the lower crust of Songpan-Ganzi block. The Diebu-Bailongjiang Fault and Guangaishan-Dieshan Fault zone extend to a shallow depth and merge into the East Kunlun Fault(Tazang segment)in the deep part. The characteristic of low-resistivity of the media in the deep-seated structures in the East Kunlun Fault(Tazang segment)is the underlying cause for the gradual decrease of horizontal slip rate and gradual increase of vertical movement of the Tazang segment. The West Qinling Fault is a main geoelectric boundary zone, which extends through the Moho; Lintan-Tanchang Fault zone behaves as a low-resistivity layer with a certain width, which extends into the low-resistivity layer in the mid to lower crust. The source region of Minxian-Zhangxian MS6.6 earthquake locates in the core of inverted "trapezoid" of the low-resistivity layer in the West Qinling orogenic belt(west segment), that is, in the contact area between the high to low resistivity layers, and also in the low-resistivity fractured zone near the Lintan-Tanchang Fault. The interaction of southwest-northeast pushing from Songpan-Ganzi block and resistance of Longxi Basin block at its northeast is external dynamics of the Minxian-Zhangxian MS6.6 earthquake, and the high- and low-resistivity medium property and their contact relation in the seismic source region of the earthquake are the internal factor to generate this earthquake.